CAPCATVAL will be focused on:
Both thermocatalytic and photoelectrocatalytic processes will be conducted to the production of platform molecules from CO2 or N2O, i.e. “building blocks”, in the chemical industry. The desired products are methane, methanol, dimethylether, light olefins, acetic acid and linear aldehydes.
The goal of this project is to increase process efficiency in order to accelerate the deployment of efficient, stable and competitive catalytic technologies. In this sense, the core of this project will be focused on:
SUBPROJECTS DATA
CAPCATVAL is a national project constituted by the Institute of Chemical Technology – CSIC (Valencia, Spain), the University of Malaga (Malaga, Spain) and the University of Valencia (Valencia, Spain), and also participate members of UNIBO-Universidad of Bologna, Bologna (Italy), UFC-Federal University of Ceará (Brazil), UFSC-Federal University of Santa Catarina (Brazil) and TU: Twente University (Netherlands)
Subproject 1 and Coordinator Project
Institute of Chemical Technology– CSIC (Valencia, Spain)
TITLE: CO2 as feedstock in thermo‐catalysis and its transformation into fuels and chemicals
IP 1 : Patricia Concepción Heydorn
IP 2 : José Manuel López Nieto
Subproject 2
University of Malaga (Malaga, Spain)
TITLE: Design of sustainable materials for N2O y CO2 capture and catalytic valorisation
IP 1: Antonia Infantes Molina
IP 2 : Enrique Rodríguez Castellón
Subproject 3
University of Valencia (Valencia, Spain)
TITLE: Catalytic and photoelectrocatalytic strategies for preventing the release of N2O and CO2 to the environment: valorisation and elimination
IP 1: Benjamín Eduardo Solsona Espriu
IP 2: Ana María Dejoz García
Published works
1) Autores: J.V.C. do Carmo, R.C.F. Bezerra, Y. Guerra, R. Peña-Garcia, A.C. Oliveira, E. Padron-Hernandez, G.D.
Saraiva, J.M. Soares, A.J.R. Castro, S.l Tehuacanaero-Cuapa, E. Rodríguez-Aguado, E. Rodríguez-Castellón
Título: Cr-containing Rare-Earth Substituted Yttrium Iron Garnet Ferrites Catalytic Properties in the Ethylbenzene Oxidation
Ref. revista: Catalysts https://doi.org/10.3390/catal12091033
Clave: Volumen: 12 Páginas, inicial: 1033 final: Fecha: 2022
2) Autores: J.V.C. do Carmo, R de Cássia, F. Bezerra, S. Tehuacanero-Cuapa, E. Rodríguez-Aguado, R. Lang, A.F.Campos, G. Duarte, G.D.Saraiva, L. Otubo, A.C.Oliveira, E. Rodíguez-Castellon
Título: Synthesis of tailored alumina supported Cu-based solids obtained from nanocomposites: Catalytic application for valuable aldehyde and ketones production
Ref. revista: Materials Chemistry and Physics https://doi.org/10.1016/j.matchemphys.2022.126800
Clave: Volumen: 292 Páginas, inicial:126800 final: Fecha: 2022
3) Autores: D. Polidoro, A. Perosa, E. Rodríguez-Castellón, P. Canton, L. Castoldi, D. Rodríguez-Padrón, M. Selva
Título: Metal-Free N Doped Carbons for Solvent-Less CO2 Fixation Reactions: A Shrimp Shell Valorization Opportunity
Ref. revista: ACS Sustainable Chemistry and Engineering https://doi.org/10.1021/acssuschemeng.2c04443
Clave: Volumen:10 Páginas, inicial: 13835 final: 13848 Fecha: 2022
4) Autores: D. Ballesteros‐Plata, J.A. Cecilia, I. Barroso‐Martín, J. Jiménez‐Jiménez, A. Infantes‐Molina, E. Rodríguez‐Castellón
Título: Materials Design for N2O Capture: Separation in Gas Mixtures
Ref. revista: Catalysts https://doi.org/10.3390/catal12121539
Clave: Volumen: 12 Páginas, inicial: 1539 final: Fecha: 2022
5) Autores: D.A. Bravo Fuchineco, A.C. Heredia, S.M. Mendoza, E. Rodríguez-Castellón, M.E. Crivello
Título: Production of Levulinic Esters by Heterogeneous Catalysis with Zr Metal−Organic Frameworks in Pressure Reactors
Ref. revista: Industrial Engineering Chemistry Research https://doi.org/10.1021/acs.iecr.2c02786
Clave: Volumen: 61 Páginas, inicial: 17821 final: 17832 Fecha: 2022
6) Autores: R.C.F. Bezerra, G. Mota, R.M.B. Vidal, J.V. do Carmo, G.D. Saraiva, A. Campos, A.C. Oliveira, R. Lang , L. Otubo, J. Jiménez Jiménez, E. Rodríguez-Castellón
Título: Effect of Basic Promoters to Porous Supported Alumina Catalysts for Acetins Production
Ref. revista: Catalysts https://doi.org/10.3390/catal12121616
Clave: Volumen: 12 Páginas, inicial: 1616 final: Fecha: 2022
7) Autores: M.R. Oliveira1, J.A. Cecilia, J.F. De Conto, S.M. Egues, Enrique Rodríguez-Castellón
Título: Rapid synthesis of MCM-41 and SBA-15 by microwave irradiation: promising adsorbents for CO2 adsorption
Ref. revista: Journal Sol Gel Technology https://doi.org/10.1007/s10971-022-06016-3
Clave: Volumen: 105 Páginas, inicial:370 final:387 Fecha: 2023
8) Autores: J.PS Nascimento, A.J. Martins, R. de C.F. Bezerra, G.M. Bertoldo, A.C. Oliveira, J.R. Bezerra, R.S. Araujo, R. Lang, L. Otubo, E. Rodríguez-Aguado, E. Rodríguez-Castellon
Título: Designed synthesis of nanostructured ZrO2 as active support for glycerol valorization reaction
Ref. revista: Ceramics International https://doi.org/10.1016/j.ceramint.2022.09.140
Clave: Volumen: 49 Páginas, inicial:1784 final:1778 Fecha: 2023
9) Autores: D. Ballesteros-Plata,Y. Zhang, E. Rodríguez Castellón,T. Vincent, E. Guibal
Título: Brown algal residue for the recovery of metal ions – Application to Cd(II), Ni(II) and La(III) sorption
Ref. revista: Advanced Sustainable Systems DOI: 10.1002/adsu.202200420
Clave: Volumen: 7 Páginas, inicial: 2200420 final: Fecha: 2023
10) Autores: J. Nascimento, R.C. Bezerra, E. Assaf, A. Lucrecio, R. Araujo, G. Saraiva, E. Rodriguez-Castellon, E. Rodriguez Aguado, G. Pinheiro, A. Oliveira.
Título: Investigation of the deactivation behavior of MeMo/La2O3-Al2O3 and MeMo/Nb2O5 supported catalysts (Me=Pt, Ni and Co) in tri-reforming of methane
Ref. revista: Energy and Fuels https://doi.org/10.1021/acs.energyfuels.2c03120
Clave: Volumen:37 Páginas, inicial:3836 final:3853 Fecha: 2023
11) Autores: D. Polidoro, D. Ballesteros-Plata, A. Perosa, E. Rodríguez-Castellón, D. Rodríguez-Padrón, M. Selva
Título: Controlled alcohol oxidation reactions by supported non-noble metal nanoparticles on chitin-derived N-doped carbons
Ref. revista: Catalysis, Science and Technology DOI: 10.1039/D3CY00082F
Clave: Volumen: 13 Páginas, inicial:2223 final: 2238 Fecha: 2023
12) Autores: E.H.C. Silva, E.S.M. Cutrim, M.R.C. Lemma, H.S. Barud, A. Rojas, L. Gómez-Hortigüela, A.S.de Menezes, E. Rodríguez-Castellón, A.A. Tanaka, A.C.S. Alcántara
Título: New insights about the intercalation of 5-Fluorouracil into 2D Mg–Al layered double hydroxide nanosheets: A theoretical and experimental investigation
Ref. revista: Journal of Drug Delivery Science and Technology https://doi.org/10.1016/j.jddst.2023.104294
Clave: Volumen:81 Páginas, inicial: 104294 final: Fecha: 2023
13) Autores: M.S. Souza, A.J. Martins, J.A.S. Ribeiro, A. Campos, A.C. Oliveira, R.F. Jucá, G.D. Saraiva, M.A.M. Torres, E. Rodríguez-Castellón, R.S. Araujo
Título: Selective Catalytic Reduction of NOx by CO over Cu(Fe)/SBA-15 Catalysts: Effects of the Metal Loading on the Catalytic Activity
Ref. revista: Catalysts doi.org/10.3390/catal13030527
Clave: Volumen: 13 Páginas, inicial: 527 final: Fecha: 2023
14) Autores: N. Spigariol, L. Liccardo, E. Lushaj, E. Rodríguez-Castellon, I. Barroso Martin, F. Polo, A. Vomiero, E. Cattaruzza, E. Moretti
Título: Titania nanorods array homojunction with sub-stoichiometric TiO2 for enhanced methylene blue photodegradation
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2023.114134
Clave: Volumen: 119 Páginas, inicial: 114134 final: Fecha: 2023
15) Autores: N. Schiaroli, L. Negahdar, M. Lützen, P.H. Ho, L.J. Allen, A. Natoli, F. Ospitali, F. Maluta, E. Rodríguez-Castellón, C.D. Damsgaard, G. Fornasari, A,M. Beale, P. Benito
Título: Efficient low-loaded ternary Pd-In2O3-Al2O3 catalysts for methanol production
Ref. revista: Journal of Catalysis https://doi.org/10.1016/j.jcat.2023.05.012
Clave: Volumen: 424 Páginas, inicial: 140 final: 151 Fecha: 2023
16) Autores: J. de Oliveira Brotto, T. Andrade Cruz, I. Pereira, J. Lutz Ienczak, R.A. Peralta, J.M. Lázaro-Martínez, H.J. José, E. Rodríguez-Castellón, R.F.P.M. Moreira
Título: Mechanistic insights and kinetics of torrefaction of pine wood biomasses using solid-state NMR
Ref. revista: Journal of Analytical and Applied Pyrolysis https://doi.org/10.1016/j.jaap.2023.106019
Clave: Volumen: 172 Páginas, inicial: 106019 final: Fecha: 2023
17) Autores: D.G. Della Rocca, M. Schneider, F.C. Fraga, A. De Noni Júnior, R.A. Peralta, E. Rodríguez-Aguado, E. Rodríguez-Castellón, R.F.P.M. Moreira
Título: A comprehensive insight into the parameters that influence the synthesis of Ag2MoO4 semiconductors via experimental design.
Ref. revista: Journal Materials Science: Materials in Electronics https://doi.org/10.1007/s10854-023-10897-7
Clave: Volumen:34 Páginas, inicial:1500 final: Fecha: 2023
18) Autores: A.P.M. Pires Alcantara, M.L. Moura de Oliveira, J.C. Santiago de Araújo, R. dos Santos Araújo, R.K. Chaves de Lima, A. Valente Bueno, M.E. Vieira da Silva, P.A. Costa Rocha, E. Rodríguez-Castellón
Título: Reduction of Typical Diesel NOx Emissions by SCR-NH3 Using Metal-Exchanged Natural Zeolite and SBA-15 Catalysts
Ref. revista: Air https://doi.org/10.3390/air1030012
Clave: Volumen: 1 Páginas, inicial: 159 final: 174 Fecha: 2023
19) Autores:R. de C.F. Bezerra, G.Mota, R.M.B. Vidal, G.D. Saraiva, A.C. Oliveira, A.J.R. Castro, R.S. Araújo, E. Rodríguez-Aguado, J. Jiménez Jiménez, E. Rodríguez-Castellón
Título: Multifunctional properties of alumina-based graphene nanocomposites as catalysts for esters of glycerol production
Ref. revista: Molecular Catalysis https://doi.org/10.1016/j.mcat.2023.113427
Clave: Volumen: 548 Páginas, inicial: 113427 final: Fecha: 2023
20) Autores: I. Barroso-Martín, N. Benmebirouk-Pareja , M. Montana, J. Antonio Cecilia, A. Infantes-Molina, E. Rodríguez-Castellón
Título: Ruthenium incorporation into hydrotalcites-derived mixed oxides for phenol hydrogenation: Role of Mg/Al molar ratio
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2023.114274
Clave: Volumen: 423 Páginas, inicial:114274 final: Fecha: 2023
21) Autores: A. Raeisi, A. Najafi Chermahini, M. Esmaeilzadeh Khabazi, M. Mohsen Momeni, R. Luque, A. Pineda, E. Rodríguez Castellón, C. Vargas Fernández
Título: Preparation of a novel BiVO4-Ni(II)/g-C3N4 bifunctional photo electrocatalyst for oxidative and absorptive desulfurization of model fuel
Ref. revista: Journal of Alloys and Compounds https://doi.org/10.1016/j.jallcom.2023.172025
Clave: Volumen: 968 Páginas, inicial: 172025 final: Fecha: 2023
22) Autores: L. Hejji, A. Azzouz, L. Pérez-Villarejo, E. Castro, S. Badredine, E. Rodríguez-Castellón
Título: Fe3O4@UiO-66-NH2 based on magnetic solid phase extraction for determination of organic UV filters in environmental water samples
Ref. revista: Chemosphere https://doi.org/10.1016/j.chemosphere.2023.140090
Clave: Volumen: 341 Páginas, inicial: 140090 final: Fecha: 2023
23) Autores: M.R. Oliveira, J.A. Cecilia, D. Ballesteros, I. Barroso-Martín, P. Núñez, A. Infantes-Molina, E. Rodríguez -Castellón
Título: Microvawe-assisted synthesis of zeolite A from metakaolinite for CO2 adsorption.
Ref. revista: International Jornal of Molecular Science https://doi.org/10.3390/ijms241814040
Clave: Volumen:24 Páginas, inicial:14040 final: Fecha: 2023
24) Autores: M.E Potter, S. Mediavilla-Madrigal, E. Campbell, L.J Allen, U. Vyas, S. Parry, A. García-Zaragoza, L.M. Martínez-Prieto, P. Oña-Burgos, M. Lützen, C.D Damsgaard, E. Rodríguez-Castellón, N. Schiaroli, G. Fornasari, P. Benito-Martin, A.M. Beale
Título: A High Pressure Operando Spectroscopy Examination of Bimetal Interactions in ‘Metal Efficient’ Palladium/In2O3/Al2O3 Catalysts for CO2 hydrogenation
Ref. revista: Angewandte Chemie International Edition https://doi.org/10.1002/anie.202312645
Clave: Volumen: on line Páginas, inicial: e202312645 final: Fecha: 2023
25) Autores: D.G. Della Rocca, A. De Noni Jr., E. Rodríguez-Aguado, R. Aparecida Peralta, E. Rodríguez-Castellón, G. Li Puma, R.F.P.M. Moreira
Título: Mechanistic insights on the catalytic ozonation of trimethoprim in aqueous phase using geopolymer catalysts produced from mining waste
Ref. revista: Journal of Environmental Chemical Engineering DOI:10.1016/j.jece.2023.111163
Clave: Volumen: 62 Páginas, inicial: e202312645 final: Fecha: 2023
26) Autores: F.C. Fraga, J.A. Cecilia, E. Rodriguez-Castellon, R.F.Moreira
Título: Photocatalytic Activity of Composites for Ethylene Degradation Under UV-A and Visible Light
Ref. revista: Chemical Engineering Transactions DOI:10.3303/CET23102019
Clave: Volumen: 102 Páginas, inicial: 109 final: 114 Fecha: 2023
27) Autores: F. Fernandes Barbosa, J.E. Tavares, A.d.R. Albuquerque, M.A. Morales Torres, E. Rodríguez-Castellón, S.B.C. Pergher,T.P. Braga
Título: Catalytic dehydration of glycerol ove Cu–Fe–Al based oxides:understanding changes in active sites through out the reaction
Ref. revista: RSC Advances https://doi.org/10.1039/D3RA05454C
Clave: Volumen: 13 Páginas, inicial:31182 final: Fecha: 2023
28) Autores: A.J. Martins de Farias, A. da Silva, A. Oliveira, J.V. do Carmo, G. Saraiva, R. Juca, M. Morales, R. Lang, J. Jimenez-Jimenez, E. Rodriguez-Castellon
Título: Catalytic Performances of the Nano FeCo Solids for Biofuel Additives Production: Incorporation of Promoters Effects on the Stability of the Catalysts
Ref. revista: Energy and Fuels https://doi.org/10.1021/acs.energyfuels.3c02881
Clave: Volumen: 37 Páginas, inicial:17328 final:17344 Fecha: 2023
29) Autores: A.F. Crespi, P.N. Zomero, A.L. Pérez, C.D. Brondino, A. Infantes Molina, Y. Garro Linck, G.A. Monti, M.A. Fernández, E. Rodríguez-Castellón, J.M. Lázaro-Martínez.
Título: Montmorillonite materials with paramagnetic metal complexes: structural studies and catalytic degradation of emerging pollutants
Ref. revista: Journal of Environmental of Chemical Engimeering https://doi.org/10.1016/j.jece.2023.111420
Clave: Volumen: 11 Páginas, inicial:111420 final: Fecha: 2023
30) Autores: M. Algueró, L. Zia, R. Jiménez, H. Amorín, I. Bretos, A. Barreto, G.H. Jaffari, E. Rodríguez-Castellón, P. Ramos, M.L. Calzada
Título: Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3-PbTiO3 films on Ni for metallic MEMS
Ref. revista: APL Energy https://doi.org/10.1063/5.0172616
Clave: Volumen: 1 Páginas, inicial: 036108 final: Fecha: 2023
31) Autores: D. Tavares Guimarães; L.M. Ramos Mendes; L.B. de Sousa Sabino; E. Sousa de Brito; E. Vilarrasa-García; E. Rodríguez-Castellón; J.A. Cecilia; I.J. da Silva Junior
Título: Partial purification of anthocyanins (Brassica oleracea var. Rubra) from purple cabbage using natural and modified clays as adsorbent
Ref. revista: Adsorption Science and Technology https://doi.org/10.1155/2023/2724122
Clave: Volumen: 2023 Páginas, inicial: 2724122 final: Fecha: 2023
32) Autores: A. Misol, I. Giarnieri, F. Ospitali, A. Ballarini, J. Jiménez-Jiménez, E. Rodríguez-Castellón, V. Rives, F. Martín Labajos, G. Fornasari, P. Benito
Título: CO2 hydrogenation over Ru hydrotalcite-derived catalysts
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2023.114362
Clave: Volumen: 425 Páginas, inicial: 114362 final: Fecha: 2024
33) Autores: D.S. Argüello, L.C. Saavedra Cabana, S.M. Mendoza, M.I. Oliva, E. Rodríguez-Castellón, N.F. Bálsamo, G.A. Eimer, M.E. Crivello.
Título: Layered double hydroxides modified by transition metals for sustainable glycerol valorization to glycerol carbonate
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2023.114415
Clave: Volumen: 427 Páginas, inicial: 114415 final: Fecha: 2024
34) Autores: D. Ballesteros Plata, G. Balestra, J. A. Cecilia, I. Barroso Martín, A. Infantes-Molina, T. Tabanelli, F. Cavani, J.M. López Nieto, M. Montaña, E. Rodríguez Castellón
Título: On the selective transformation of ethanol over Mg- and/or La-containing mixed oxides catalysts
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2023.114470
Clave: Volumen: 429 Páginas, inicial: 114470 final: Fecha: 2024
35) Autores: J. Cáceres-Murillo, P. Díaz-Carrasco, A. Kuhn, E. Rodríguez-Castellón, F. García-Alvarado
Título: Improvement of the rate capability of the Li4Ti5O12 anode material by Li+ exsolution and modification of the surface composition
Ref. revista: Journal of Alloys and Compounds https://doi.org/10.1016/j.jallcom.2023.173051
Clave: Volumen: 976 Páginas, inicial: 173051 final: Fecha: 2024
36) Autores: M. Algarra, C. Carrillo, M. Nešić, J.F. Tričković, J. Žakula, L. Korićanac, J. Jiménez-Jiménez, E. Rodriguez-Castellón, T.J. Bandosz, M. Petković, J. Soto
Título: Testing of black-carrots-derived fluorescence imaging and anti-metastatic potential
Ref. revista: Journal of Molecular Structure https://doi.org/10.1016/j.molstruc.2023.137245
Clave: Volumen: 1300 Páginas, inicial:1372245 final: Fecha: 2024
37) Autores: C.M Subramaniyam, A. Kuhn, E. García González, O. Guerrero-Pérez, E. Rodríguez-Castellón, F. García-Alvarado
Título: Cost Effective Synthesis of 3-Dimensional V4O9: A Promising High-Capacity Lithium Cathode
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2024.114507
Clave: Volumen: On line Páginas, inicial:114507 final: Fecha: 2024
38) Autores: M.R. Oliveira, Y. Teles Barbosa, T.S. Lima Da Silva, J.A. Cecilia , E. Rodríguez-Castellón, S.M. Egues, J.F. De Conto
Título: One-pot synthesis and surfactant removal from MCM-41 by microwave irradiation
Ref. revista: Molecules https://doi.org/10.3390/molecules29020460
Clave: Volumen: 29 Páginas, inicial: 460 final: Fecha: 2024
39) Autores: V. Bressi, F. Minio, A.M. Balu, E. Rodríguez-Castellón, A. Marrocchi, L. Vaccaro, C. Espro, S.M. Osman, R. Luque, T. Chhabra
Título: Brewing sustainability: Continuous flow Ru-supported hydrochar from bagasse beer waste for renewable N-containing chemicals via reductive amination of biomass-derived platform molecules
Ref. revista: Sustainable Chemistry and Pharmacy https://doi.org/10.1016/j.scp.2024.101436
Clave: Volumen: 37 Páginas, inicial: 460 final:101436 Fecha: 2024
40) Autores: M. S. Leguizamón-Aparicio, J.J. Musci, M. Montaña], L.J. Méndez[, M.L. Barbelli, H.P. Bideberripe, E. Rodríguez-Aguado, J.A. Cecilia, E. Rodríguez-Castellón, I.D. Lick, M.L. Casella
Título: Transformation of levulinic acid into gamma-valerolactone with ruthenium-supported catalysts. Study of the variables affecting conversion
Ref. revista: ChemCatChem https://doi.org/10.1002/cctc.202301719
Clave: Volumen: on line Páginas, inicial: e202301719 final: Fecha: 2024
41) Autores: D.A.S. Maia, T.M. Azevedo, D.S. Pereira, R.A.M. Castro, B.O. Nascimento, E. Rodríguez-Castellón, M. Bastos-Neto, D.C.S. Azevedo
Título: Water vapor adsorption on small pore ion-exchanged zeolites
Ref. revista: Adsorption https://doi.org/10.1007/s10450-024-00442-1
Clave: Volumen: on line Páginas, inicial: final: Fecha: 2024
42) Autores: D.A. Valdivieso-Vera, G.A. Flores-Escamilla, J.J. Cano-Gómez, I. Barroso-Martín, E. Rodríguez-Castellón, I.A. Santos-López, M.O. Guerrero-Pérez
Título: Effect of Nb as dopant of hydrotalcite catalysts during the ethanol condensation to optimize n-Butanol production
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2024.114658
Clave: Volumen: 433 Páginas, inicial:114658 final: Fecha: 2024
43) Autores: F. Zorzetto, D. Ballesteros-Plata, A. Perosa, E. Rodríguez-Castellón, M. Selva, D. Rodríguez-Padrón
Título: Orthogonal assisted tandem reactions for the upgrading of bio-based aromatic alcohols using chitin derived mono and bimetallic catalysts
Ref. revista: Green Chemistry https://doi.org/10.1039/D3GC04848A
Clave: Volumen: On line Páginas, inicial: final: Fecha: 2024
44) Autores: P. Jabbari, A.N. Chermahini, R. Luque , A. Pineda , E.Rodríguez Castellón
Título: Synthesis of Cu-doped TiO2 modified BiVO4 for photocatalytic oxidative desulfurization (PODS) of a model fuel
Ref. revista: Journal of Photochemistry & Photobiology, A: Chemistry https://doi.org/10.1016/j.jphotochem.2024.115625
Clave: Volumen: 452 Páginas, inicial: 115625 final: Fecha: 2024
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